Orientational Glass Transition in (KBr)1-x(KCN)x Quadrupolar Glasses: A Raman Scattering Study

Using Raman drop abstracts we accept advised the orientational bottle alteration in (KBr)1-x(KCN)x alloyed crystals with concentrations x = 0.10, 0.25 and 0.50. The dynamical rotational ataxia in the artificial appearance after-effects in able burning furnishings in the cyanide libration approach empiric in the low-frequency ashen region, about ν simeq 50 cm-1. The freezing of the orientational degrees of abandon acutely shows up in a abatement of the libration width. At aerial frequency, ν = 2076 cm-1, the inhomogeneous adorning of the CN- addition beating reflects accretion accidental ache fields after to the orientational glasses transition.

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